{"created":"2023-06-20T14:21:27.879037+00:00","id":159,"links":{},"metadata":{"_buckets":{"deposit":"1196288c-3527-45a9-8f44-d10875192fe3"},"_deposit":{"created_by":3,"id":"159","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"159"},"status":"published"},"_oai":{"id":"oai:sendai-u.repo.nii.ac.jp:00000159","sets":["7:107"]},"author_link":["470"],"control_number":"159","item_1697704552643":{"attribute_name":"タイトル（英）","attribute_value_mlt":[{"subitem_title":"Studies on the Diffusion of the Electrolytes in Organism(I) : Determination of the Diffusion Constants of Acetylcholine Chloride in NaCl Solution"}]},"item_1697706216397":{"attribute_name":"著者（英）","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kumasaka,Shigetaro","creatorNameLang":"en"}]}]},"item_2_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1973-10-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"62","bibliographicPageStart":"55","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"仙台大学紀要"},{"bibliographic_title":"Bulletin of Sendai College"}]}]},"item_2_description_10":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"(1)筆者は,塩化アセチルコリンの拡散定数を,初濃度0.0181g/mlから0.0449g/mlの範囲で,また,塩効果のために0.35モルの塩化ナトリウムを添加して測定した。この場合,添加塩濃度を一定にして測定した。(2)それぞれの濃度の拡散係数は,Beckmann-Rosenbergの方法および細野-桜田の方法を用いて算出したが,k_Dの値が著じるしく大きくなった。(3)とくにBeckmann-Rosenbergの方法による濃度依存係数k_<DBR>は,初濃度の変化に対応して変化することが明らかになった。すなわち,D_C=D_0(AC√<C_0>+BC+1)で一般化でき,本実験の条件においては,D_C=D_0(225.49C√<C_0>-57.50C+1)が成立する。ただし,D_C:濃度Cに対する拡散係数,D_0:初濃度C_0の溶液の極限希薄濃度における拡散係数(拡散定数),A,B:物質によって定まる実験定数とする。"}]},"item_2_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03893073","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"熊坂, 繁太郎"},{"creatorName":"クマサカ, シゲタロウ"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-03-07"}],"displaytype":"detail","filename":"KJ00005443813.pdf","filesize":[{"value":"779.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00005443813.pdf","url":"https://sendai-u.repo.nii.ac.jp/record/159/files/KJ00005443813.pdf"},"version_id":"b04a66cd-c1d1-4538-9d46-48ad6a884ac6"}]},"item_title":"生体電解物質の拡散の研究(第1報) : 塩化ナトリウム溶液中での塩化アセチルコリンの拡散定数の決定","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"生体電解物質の拡散の研究(第1報) : 塩化ナトリウム溶液中での塩化アセチルコリンの拡散定数の決定"}]},"item_type_id":"2","owner":"3","path":["107"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-03-07"},"publish_date":"2017-03-07","publish_status":"0","recid":"159","relation_version_is_last":true,"title":["生体電解物質の拡散の研究(第1報) : 塩化ナトリウム溶液中での塩化アセチルコリンの拡散定数の決定"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-11-20T04:59:47.767631+00:00"}